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  1. University of Yangon
  2. Department of Physics

PREPARATION OF Ga-DOPED Li7La3Zr2 O12 SOLID ELECTROLYTE FOR LITHIUM-ION BATTERYAPPLICATION

http://hdl.handle.net/20.500.12678/0000002265
http://hdl.handle.net/20.500.12678/0000002265
75189bb1-9e80-44e0-8733-0570a15aa4fb
b1e5cc50-34bc-4017-b484-2ead0de4e095
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Preparation Preparation of Ga-Doped Li7La3Zr2O12 solid electrolyte for Lithium-Ion Battery application.pdf (1120 Kb)
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Title
Title PREPARATION OF Ga-DOPED Li7La3Zr2 O12 SOLID ELECTROLYTE FOR LITHIUM-ION BATTERYAPPLICATION
Language en
Publication date 2015
Authors
Gimpaya, Ruziel Larmae T.
Cervera, Rinlee Butch M.
Description
Nowadays, most commercially available Li-ion batteries utilize combustible organic solvent-based electrolyte. This hinders its larger-scale applications such as in electric vehicles and electrical power storage systems primarily due to safety concerns. Among other possible alternatives, Li7La3Zr2O12 (LLZ) gained increasing attention on account of its good chemical stability with Li anode and high ionic conductivity. Conventional solid-state synthesis of Li7_3xGaxLa3Zr2O12 with mole fractions x= 0.00, 0.10, 0.20 and 0.30 at varying sintering time and temperature were performed in an attempt to improve the microstructure and electrochemical properties. X-ray Diffraction (XRD) results have shown that upon Ga-doping the cubic-phased LLZ was stabilized. Without Ga, a tetragonal-phased LLZ was formed at similar synthesis condition. Scanning Electron Microscopy (SEM) images have shown that Ga acts as a sintering aid. Upon comparison with pure LLZ which was synthesized in similar manner, Ga-doped LLZ exhibits reduced visible pores and better contact among particles. Increasing the amount of Ga dopant and addition of Li source promote densification and grain agglomeration.
Keywords
Li7La3Zr2O12, Ga-doped
Identifier https://uyr.uy.edu.mm/handle/123456789/440
Journal articles
8th AUN/SEED-Net Regional Conference on Electrical and Electronics Engineering
Conference papaers
Books/reports/chapters
Thesis/dissertations
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