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Anomaly of the Raman Linewidth of the Internal v2 Mode near the Phase Transition Point of K3D(SO4)2

http://hdl.handle.net/20.500.12678/0000002370
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b65b50e6-35ee-492a-af2f-b24317abf13f
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Title Anomaly of the Raman Linewidth of the Internal v2 Mode near the Phase Transition Point of K3D(SO4)2
Language en
Publication date 1994
Authors
Pho Kaung
Kasahara, Masaru
Yagi, Toshirou
Description
The linewidth of the internal mode ν 2 of SO 4 2- ion of the antiferroelectric K 3 D(SO 4 ) 2 shows the anomalous broadening with lowering temperature near the phase transition point. The broadening is well explained by a mechanism resembling the motional narrowing phenomenon in the nuclear magnetic resonance theory. The characteristic time of the motion of deuteron in a hydrogen bond is estimated to be on the order of 10 -13 s.
Identifier http://uyr.uy.edu.mm/handle/123456789/30
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