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Ferroelastic-Superprotonic Phase Transition of [K3]x[(NH4)3]1-xH(SO4)2 Single Crystal Studied by Raman Scattering

http://hdl.handle.net/20.500.12678/0000002246
9d1f2f17-424c-4694-a833-2bf7dcaa66b8
e9799716-f88f-4625-893d-3276586f82aa
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Ferroelastic-Superprotonic Ferroelastic-Superprotonic phase....pdf (3311 Kb)
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Journal article
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Title
Title Ferroelastic-Superprotonic Phase Transition of [K3]x[(NH4)3]1-xH(SO4)2 Single Crystal Studied by Raman Scattering
Language en
Publication date 2004
Authors
Win Kyaw
Ye Chan
Ohn Than
Pho Kaung
Sein Htoon
Description
Vibrational modes of the sulphate ion in mixed crystals, [K3]x[(NH4)3]1-xH(SO4)2 of Tripotassium Hydrogen Disulphate, K3H(SO4)2 and Triammonium Hydrogen Disulphate, (NH4)3H(SO4) were studied by Raman Scattering Spectroscopy. The V1 - mode frequency of the sulphate ion at room temperature is found to be shifted downwards with different crystalline environments contributed by the increase of countercation K3+ content. The temperature dependence of frequencies and that of linewidths of the V1 mode show anomalous changes near the ferroelasticsuperprotonic phase transition temperature. Critical slowing-down of the H...SO4 defect motion is observed.
Keywords
Mixed Crystals of Tripotassium Hydrogen Disulphate and Triammonium Hydrogen Disulphate
Identifier https://uyr.uy.edu.mm/handle/123456789/531
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1
Journal of the Asia Research Centre
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